POTENSI RISET DAN PENGEMBANGAN FePO4 DARI BAHAN BAKU LOKAL Fe2O3 DI INDONESIA
DOI:
https://doi.org/10.29122/mipi.v14i1.3785Abstract
Riset dan pengembangan baterai lithium mulai banyak dilakukan di Indonesia sejak awal dekade 2000-an. Diantara salah satu material yang dikembangkan adalah bahan aktif katoda LiFePO4,dengan harapan bahwa seluruh bahan baku pembuatan LiFePO4 diperoleh dari sumberdaya lokal. Sumber-sumber bahan baku LiFePO4 sendiri adalah LiOH atau LiOH.H2O atau Li2CO3 atau CH3COOLi sebagai sumber Li, Fe2O3 sebagai sumber Fe, dan H3PO4 sebagai sumber PO43-. Diantara berbagai sumber bahan baku tersebut, Fe2O3 dan H3PO4 dapat diperoleh dari dalam negeri, namun sumber lithium masih harus impor. Oleh sebab itu, produksi LiFePO4 kedepannya tidak dapat 100% menggunakan bahan baku lokal. Namun, terdapat satu cara yang dapat dilakukan agar menggunakan 100% bahan baku lokal, yaitu pengembangan FePO4. FePO4 ini nantinya berpotensi untuk diproduksi dan diekspor sebagai bahan baku pembuatan LiFePO4. Disamping itu, FePO4 juga memiliki nilai tambah lain sebagai bahan pelapis pencegah oksidasi pada permukaan logam. Oleh sebab itu, material ini cukup strategis untuk dikembangkan di Indonesia.
References
Balogun, M. S., Qiu, W., Luo, Y., Meng, H., Mai, W., Onasanya, A., Olaniyi, T. K., Tong, Y., A Review of the Development of Full Cell Lithium-ion Batteries: the Impact of Nanostructured Anode Materials, Nano Research, Vol. 9, No. 10, 2016, p. 2823-2851.
Zhang, Q., Liu, K., Ding, F., Liu, X., Recent Advances in Solid Polymer Electrolytes for Lithium Batteries, Nano Research, Vol. 10, No. 12, 2017, p. 4139-4174.
Writer, B., Lithium-ion Batteries: a Machine-generated Summary of Current Research, Springer, Cham, Switzerland, 2019.
Choudhury, S., Rational Design of Nanostructured Polymer Electrolytes and Solid-Liquid Interphases for Lithium Batteries, in Springer Theses, Springer, 2019.
Imanishi, N., Luntz, A. C., Bruce, P., The Lithium Air Battery: Fundamentals, Springer, New York, NY, United States, 2014.
Triwibowo, J., Priyono, S., Purawiardi, I., Lestariningsih, T. Ratri, C. R., Study on Electrochemical Performance of Carbon-coated LiFePO4 as Cathode Material for Lithium Ion Batteries, AIP Conference Proceedings, Vol. 1755, No. 1, 2016, p. 150009.
Triwibowo, J., Yuniarti, E., Suharyadi, E., The Characteristic of Carbon-coated LiFePO4 as Cathode Material for Lithium Ion Battery Synthesized by Sol-gel Process in One Step Heating and Varied pH, AIP Conference Proceeding, Vol. 1617, No. 1, 2014, p. 52-56.
Triwibowo, J., Alamsyah, I., Setiawan, J., Synthesis and Characterization of Carbon-coated LiFePO4 with Various Carbon Sources as Cathode Material for Lithium Ion Batteries through a Solid-state Process, Materials Science Forum, Vol. 827, 2015, p. 186-191.
Triwibowo, J., Priyono, S., Purawiardi, I., Ratri, C. R., Suwandi, E., Electrochemical Performance of LiFe1-xMnxPO4 (x = 0, 0.10, 0.15, 0.2) Synthesized by Solid State Process as Cathode Material for Li-ion Battery, AIP Conference Proceedings, Vol. 1712, No. 1, 2016, p. 050015.
Triwibowo, J., Setiawan, J., Purawiardi, I., Prihandoko, B., Study on Carbon-coated LiMn0.7Fe0.3-xNixPO4 (0 ≤ x ≤ 0.15) as Cathode Material for Lithium Ion Batteries, Materials Science Forum, Vol. 827, 2015, p. 140-145.
Firnadya, S. A., Syahrial, A. Z., Subhan, A., Enhancing Battery Performance by Nano Si Addition to Li4Ti5O12 as Anode Material on Lithium-ion Battery, Ionics, Vol. 24, No. 4, 2018, p. 1029-1037.
Setiawan, D., Subhan, A., Saptari, S. A., Ca-doped LTO Using Waste Egghells as Ca Source to Improve the Discharge Capacity of Anode Material for Lithium-ion Battery, AIP Conference Proceedings, Vol. 1862, No. 1, 2017, p. 030073.
Noerochim, L., Fikry, R., Nurdiansah, H., Purwaningsih, H., Subhan, A., Synthesis of Dual-phase Li4Ti5O12-TiO2 Nanowires as Anode for Lithium-ion Battery, Ionics, Vol. 25, No. 4, 2019, p. 1505-1511.
Wigayati, E. M., Lestariningsih, T., Subhan, A., Ratri, C. R., Purawiardi, I., Synthesis and Characterization of LiBOB as Electrolyte for Lithium-ion Battery, Ionics, Vol. 22, No. 1, 2016, p. 43-50.
Wigayati, E. M., Ratri, C. R., Purawiardi, I., Rohman, F., Lestariningsih, T., Microstructure Analysis of Synthesized LiBOB, Indonesian Journal of Chemistry, Vol. 15, No. 3, 2015, p. 242-247.
Wigayati, E. M., Lestariningsih, T., Ratri, C. R., Purawiardi, I., Prihandoko, B., Synthesis of LiBOB Fine Powder to Increase Solubility, Makara Journal of Technology, Vol. 21, No. 1, 2017, p. 26-32.
Wigayati, E., Ridlo, R., Subhan, I., Purawiardi, I., Synthesis and Characterization of PVdF-LiBOB Electrolyte Membrane with ZrO2 as Additives, The Journal of Pure and Applied Chemistry Research, Vol. 6, No. 3, 2017, p. 228.
Prasetyo, A. B., Prasetiyo, P., Matahari, I., Pembuatan α-Fe2O3 dari Hasil Pengolahan Bijih Besi Primer Jenis Hermatit untuk Bahan Baku Baterai Lithium, Metalurgi, Vol. 29, No. 3, 2014, p. 179-190.
Si, X., Li, M., Fu, X., An Improved Method to Prepare FePO4 by Introduction Na3PO4 and its Usage for Fabricating LiFePO4, Journal of Wuhan University of Technology – Mater. Sci. Ed., Vol. 34, No. 5, 2019, p. 1097-1102.
Zhu, Y., Tang, S., Shi, H., Hu, H., Synthesis of FePO4.xH2O for Fabricating Submicrometer Structured LiFePO4/C by a co-Precipitation Method, Ceramics International, Vol. 40, 2014, p. 2685-2690.
Chen, C., Liu, G. B., Wang, Y., Li, J. L., Liu, H., Preparation and Electrochemical Properties of LiFePO4/C Nanocomposite using FePO4.2H2O Nanoparticles by Introduction of Fe3(PO4)2.8H2O at Low Cost, Electrochimica Acta, Vol. 113, 2013, p. 464-469.
Yang, X., Zhang, S. M., Zhang, J. X., Synthesis and Modification of Iron-based Cathode Materials: Iron Phosphate for Lithium Secondary Batteries, Arab. J. Sci. Eng., Vol. 39, 2014, p. 6687-6691.
H. Hu, Y. Wang, Y. Huang, H. B. Shu, X. Y. Wang., Na2FePO4F/C Composite Synthesized via a Simple Solid-state Route for Lithium-ion Batteries, J. Cent. South Univ., Vol. 26, 2019, p. 1521-1529.
Downloads
Published
How to Cite
Issue
Section
License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Open Access Policy
MIPI provides immediate open access to its content on the principle that making research freely available to the public supports a greater global exchange of knowledge.
MIPI by BRIN is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License. Permissions beyond the scope of this license may be available at http://ejurnal.bppt.go.id/index.php/MIPI
