Leakage Investigation on a Fired Heater Tube of a Petroleum Refinery due to Carburization
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Abstract
The fired heater of a petroleum processing refinery leaks in one of the convection tubes. The tube is made of ASTM A-106 Gr.B. Process fluid in the tube is xylene with a design pressure of 15.8 kg/cm²g and design temperature of 299 °C (at the inlet) and 405 °C (at the outlet). This study aims to determine the type and causes and the mechanism of leakage in the tube. A number of tests have been carried out including visual inspection and macroscopic analysis, chemical analysis, metallographic and hardness testing, and SEM (scanning electron microscopy) analysis which is equipped with EDS (energy dispersive spectroscopy). The results obtained showed that the leak that occurred in the convection tube was caused by carburization and metal dusting. Carburization occurs in the inner walls of the tube that experience some localized overheating due to the formation of coke deposits.
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References
Metals Handbook, “Properties and Selection: Irons, Steels, and High Performance Alloys”, ASM International, Materials Park, vol.1, 10th edn. pp. 617-652, 1990
D.N. Adnyana, “Metallurgical examination and life-time assessment of high pressure steam pipes”, J. Sci. Technol. Metall. 33 (3), 109-124, 2018
American Petroleum Institute Standard 530, “Calculation of Heater Tube Thickness in Petroleum Refineries”, Washington DC, 5th edn., pp. 48-49, 2004
American Petroleum Institute RP 571, “Graphitization and Softening (Spheroidization)”, Washington DC, 1st edn., pp. 1-7, 2003
American Petroleum Institute RP 571, “Carburization”, Washington DC, 1st edn, pp. 4-113 to 4-115, 2003
H.J. Grabke, “Carburization, carbide formation, metal dusting, coking”, Materiali in Technologiye, 36 (6), 297 - 305, 2002.
C.A.Loto, R.T.Loto and A.P.I. Popoola, “An investigation of carburization resistance performance of ethylene furnace tube alloys”, Int. J. Physical Sci., 6 (19), 4596-4607, 2011.
T. Chowwanorothapunya and C. Peeratatsuwan, “The study on high temperature degradation of AISI 1020 low carbon steel in the carburization state”, RMUTP Research Journal, 1 (2), 22-29, 2016
G.F. Samaras and G.N. Haidemenopoulos, “Carburization of high-temperature steels: A simulation-based ranking of carburization resistance”, J. Case Stud. Eng. Fail. Anal. 51, 29-36, 2015
American Petroleum Institute RP 571, Metal Dusting, Washington DC, 1st edn., pp. 4-118 to 4-120, 2003
ASM Handbook, “Metallography and Microstructures”, ASM International, Materials Park, vol. 9, 6th print. pp. 165-196, 210-216, 1995
ASME BPVC Section II Part A, “Ferrous Materials Specifications”, The American Society of Mechanical Engineers, New York, NY, pp. 205-220, 2007
ASM Handbook, “Failure Analysis and Prevention,” ASM International, Materials Park, vol. 11, 6th edn, pp. 1838-1849, 1998
D.N. Adnyana, “Failure of a heat exchanger return bend due to long-term localized overheating”, J. Sci. Technol. Metall. 34 (1), 19-30, 2019
A.P. Watkinson, “Deposition from crude oils in heat exchangers”, Proc. 6th Int. Conf. Heat Exchanger Fouling and Cleaning, Kloster Irsee, Germany, pp. 7-16, 2005
W. Wang and A.P. Watkinson, “Iron sulphide and coke fouling from sour oils: Review and initial experiments”, Proc. Int. Conf. Heat Exchanger Fouling and Cleaning, Crete Island, Greece, pp. 23-30, 2011