Pemanfaatan Limbah Industri Baja sebagai Bahan Baku Pembuatan Logam Pig Iron : Peleburan Mill Scale Menggunakan Submerged Arc Furnace [Utilization of Steel Making Industrial Waste to Produce Pig Iron: Smelting Process of Mill Scale Using Submerged Arc...]
Main Article Content
Abstract
Mill scale is a by-product that resulted from the steel making industries containing iron oxides, such as hematite (Fe2O3), magnetite (Fe3O4) and wustite (FeO). The smelting process of mill scale into pig iron as secondary raw material for the steel making process has conducted. A 30 Kg of mill scale which crushed into -40 mesh, 0-6 kg amount of coal (internal reductant) and 2 wt.% (0.6 kg) of bentonite (binder) were mixed homogeneously and agglomerated using briquette machine. The composite briquette had been smelting together with 7-8 kg of coke (external reductant) and 0-4.5 kg of limestone (flux) using submerged arc furnace. The smelting process was carried out for 45 minutes, and the pouring temperature was 1450-1500 ºC. The study of coal addition in composite briquette, amount of cokes and limestone addition in the smelting process of mill scale has been investigated clearly. The optimum specified consumption energy of smelting process of mill scale was 3.64 kWh/kg product, resulted from the smelting of 30 kg of mill scale with 0% coal addition in composite briquette together with 3 kg (10 wt.%) lime stones and 7 kg of cokes (stoichiometric) addition. The optimum basicity for smelting a mill scale was 1.0. The pig iron which resulted from smelting the mill scale could promote as a raw material for producing grey cast iron, white cast iron, and malleable cast iron.
Article Details

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
References
M. A. Legodi, D. de Waal, “The preparation of magnetite, goethite, hematite and maghemite of pigment quality from mill scale iron waste,” Dyes and Pigments, vol. 74, 161-168, 2007.
Z. Zulhan, “Aspek teknologi dan ekonomi pembangunan pabrik pengolahan bijih besi menjadi produk baja di Indonesia,” Majalah Metalurgi, V, hal. 105-120, 2013.
R. Sen, S. Dehiya, U. Pandel, M. K. Banerjee, “Utilization of low grade coal for direct reduction of mill scale to obtain sponge iron: effect of reduction time and particle size,” Procedia Earth and Planetary Science, 11, pp. 8-14, 2015.
T. P. Rahman, A. Sukarto, N. T. Rochman, A. Manaf, “Sintesis pigmen besi oksida berbahan baku limbah industri baja (mill scale),” Jurnal Fisika, Vol. 3, hal. 86-89, 2013.
A. Fiandimas dan A. Manaf,” Pembuatan magnet permanen barium heksaferit berbahan baku mill scale dengan teknik metalurgi serbuk,” Jurnal Sains Materi Indonesia, Vol. 5, hal. 45-50, 2003.
O. Benchiheub, S. Mechachti, S. Serrai, M. G. Khalifa,” 2010. Elaboration of iron powder from mill scale,” J. Mater. Environ. Sci, Vol. 4, pp. 267-276, 2010.
R. Farahat, M. Eissa, G. Megahed and A. Baraka, “Reuction of mill scale generated by steel processing,” Journal of Steel and Related Materials: Steel Grips, Vol. 8, 2010.
B. D. Flores, I. V. Flores, M. C. Bagatini, E. Osorio, A. C. F Vilela, “Study on reducing and melting behavior of mill scale/petroleum coke blend’” Tecnol. Metal. Mater. Miner., Vol. 10, pp. 365-374, 2013.
S. Saberifar, F. Jafari, M. A. Jafarzadeh, S. A. Mousavi, “Recycling Evaluation of Mill Scale in Electric Arc Furnace.,” Journal of Advanced Materials and Processing, Vol. 2, pp. 73-78, 2014.
M. Eissa, A. Ahmed, M. El-Fawkhry, “Conversion of Mill Scale Waste into Valuable Products via Carbothermic Reduction,” Journal of Metallurgy, Vol. 2015, pp. 1-9, 2015.
N. Gade, G. Verma, R. Sen, U. Pandel, ”Effect of Calcium Carbonate on The Reduction Behaviour of Mill Scale,” Proceedia Earth and Planetary Science, Vol. 11, pp. 319-324, 2015.
J. R. Davis, “Classification and Basic Metallurgy of Cast Iron” in ASM Specialty Handbook Cast Irons. ASM International,1996. pp. 3-15.