KINETIKA REAKSI PELARUTAN NIKEL DARI KALSIN NIKEL LATERIT [Kinetics of Nickel Dissolution from Nickel Laterite Calcine]

Main Article Content

Rudi Subagja

Abstract

At present work, an experiment to investigate a kinetics of nickel dissolution from nickel laterit calcine into the aqueous sulphuric acid solutions were carried out by using the nickel laterites calcine which was prepared by reduction roasting of nickel laterites oresby using 10% coal as reducing agents at temperature 800 °C. The dissolution test were caried out by using I litre capacities of glass reactor, with the experimental conditions: a) a sulphuric acid concentration 0,1 mole/litre, b) aeration rate were varied from 0 litre/menit up to 1 litre/menit, c)dissolution temperatures were varied from 40 °C up to 70 °C and reaction time were from 15 minutes up to 240 minutes. From the result of experiment, it is found that the dissolution of nickel from nickel laterite calcine into the aqueous sulphuric acid solutions increased when the aeration rate were increased from 0 litre/minute to I litre/minute, the dissolution temperatures were increased from 40 °C to 70 °C. From the kinetics study, it is found that the dissolution of nickel from nickel laterites calcines in to the aqueous sulphuric acid solutions follows the diffusion processcontrolled with activated energy 26.73 Kj/mole.

Article Details

How to Cite
Subagja, R. (2015). KINETIKA REAKSI PELARUTAN NIKEL DARI KALSIN NIKEL LATERIT [Kinetics of Nickel Dissolution from Nickel Laterite Calcine]. Jurnal Metalurgi, 30(2), 71–80. https://doi.org/10.14203/metalurgi.v30i2.38
Section
Articles

References

Oxley Anne & Barcza Nic, “Hydro-pyro integration in the processing of nickel laterite,” International Journal of Minerals Engineering., 54, hal. 2-13, 2013.

Shailesh, “a century of discoveries, inventors, and new Nickel alloys,” Journal of Metal., September, hal. 18-20, 2006.

Lewis E Shoemaker and Gaylord D. Smith, “a century of Monel Metal: 1906-2006,” Journal of Metal., September, hal. 22-26, 2006.

www.kemenperin.go.id, diunduh 15 juni 2015.

Rhamdhani, M.A., Hayes, P.C., Jak, E, “Nickel laterite Part 1 – microstructure and phase characterizations during reduction roasting and leaching,” Miner. Process. Extr. Metall. Rev. 3., Vol. (118), hal. 129–145, 2009.

Anne & Barcza Nic, “Hydro-pyro integration in the processing of nickel laterite,” International Journal of Minerals Engineering., 54, hal. 2-13, 2013.

Dalvi, A.D., Bacon, W.G., Osborne, R.C, “The past and future of nickel latertites,” In: PDAC 2004 International Convention., March 7–10, hal. 1–27, 2004.

Departemen Pertambangan dan Energi, “Potensi dan Prospek Investasi di Sektor Pertambangan dan Energi 1998-1999,” 1998.

Peta Ekonomi Mineral Dit. Sumber daya Mineral Republik Indonesia, 1997.

G. Senanayake, J. Childs, B.D. Akerstrom, D. Pugaev, “Reductive acid leaching of laterite and metal oxides — A review with new data for Fe(Ni,Co)OOH and a limonitic ore,” Hydrometallurgy., Vol. 110, hal. 13–32, 2011.

R.G. McDonald , B.I. Whittington, “Atmospheric acid leaching of nickel laterites review, Part I. Sulphuric acid technologies,” Hydrometallurgy., Vol. 91, hal. 35–55, 2008.

R.G. McDonald , B.I. Whittington, “Atmospheric acid leaching of nickel laterites review. Part II. Chloride and biotechnologies,” Hydrometallurgy., Vol. 91, hal. 56–69, 2008.

R.A. Bergman, “Nickel production from low iron laterite ores: Process description,” CIM. Bulletin., Vol. 96. no. 1072, hal. 127-138, 2003.

C.S Simons, “The production of nickel: Extractive Metallurgy – Past, present and future, Extractive Metallurgy of nickel and cobalt,” Prosidings of a sympoium, The Metallurgical society, CP Tyrorer and C.A landolt ed, TMS Annual meeting., Phoenic Arizona, hal. 91-134, 1988.

C.M Diaz, C.A Landolt, A Vahed, A.E.M Warner and J.C Taylor, “ Extractive metallurgy of Nickel and Cobalt,” Procceeding of symposium, C.P. Tyroler and C.A Landolt Ed, The Metallurgical society., May, hal. 211- 239, 1988.

Rudi Subagja, “Potensial – pH diagram sistem Cu-Fe-H2O berbasis komputer,” Prosiding Seminar Material Metalurgi, Pusat Penelitian Metalurgi LIPI., Desember, hal. 311- 319, 2013.

Octave Levenspiel , “Chemical reaction engineering,” 2nd ed, Wiley International ed, New York, 1972.

Wyadysyawa Mulak, Beata Miazga, Anna Szymczycha, “Kinetics of nickel leaching from spent catalyst in sulphuric acid solution,” Int. J. Miner. Process., Vol 77, Hal. 231– 235, 2005.