Penurunan Kadar Torium dan Radioaktivitas dalam Limbah Cair Proses Pengolahan Monasit PLUTHO Menggunakan Koagulan FeSO4
Main Article Content
Abstract
The separation of radioactive and rare earth mineral carried out in PLUTHO produces waste that still contains thorium and uranium. The resulting waste requires further processing to be environmentally friendly. The purpose of study is to reduce thorium content and radioactivity in liquid waste of PLUTHO monazite treatment process using ferro sulphate coagulant. PLUTHO Pilot Plant is one of facility that built to dissociate uranium, thorium and light rare earth from mineral of monazite. Variations of treatments applied in the research are coagulant dosage and pH. Thorium content is measured by Spectrophotometer UV-Vis method, whereas radioactivity is measured by radiation counting meter Ludlum Model 1000 Scaler. The result shows that the optimum condition of coagulation is in pH 8,0 with concentration of ferro sulphate 225 mg/L which may reduce thorium content up to 45,20 % and reduce radioactivity to 100 % out of its initial thorium content and radioactivity as much as 0,73 mg/L and 1,35 Bq/g, respectively.
Article Details

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
1. Introduction
By using or sharing content from EKSPLORIUM - Buletin Pusat Pengembangan Bahan Galian Nuklir ("the Journal"), you agree to follow these Terms and Conditions. The Journal's content is licensed under the Creative Commons Attribution-NonCommercial-ShareAlike (CC BY-NC-SA) license. If you do not agree to these terms, please do not use the content.
2. How You Can Use the Content
-
Share: You can copy, share, and distribute the work, but only for non-commercial purposes.
-
Adapt: You can change, remix, or build on the work, as long as it is for non-commercial purposes and you share it under the same license (CC BY-NC-SA).
3. Attribution (Giving Credit)
When you use or share the content, you must:
-
Give proper credit to the author(s).
-
Mention the title of the work and the journal name.
-
Provide a link to the license (https://creativecommons.org/licenses/by-nc-sa/4.0/).
-
Indicate if you made any changes to the work.
4. Non-Commercial Use
You cannot use the work to make money or for any commercial activities. For example, you cannot sell or use the content in advertisements.
If you want to use the content for commercial purposes, you need to get permission from the author(s) or the publisher.
5. ShareAlike
If you make changes to the content (like creating a new version or remixing it), you must share your new version under the same CC BY-NC-SA license.
6. Exclusions
Some materials in the Journal may have different licenses or restrictions, such as third-party content (like images or datasets). You must respect the rules for those materials.
7. No Warranty
The content is provided "as is." The authors and publisher do not guarantee that the content is error-free or suitable for any specific purpose. Use the content at your own risk.
8. Modifications and Withdrawal of Content
The publisher and authors can update or remove content at any time. If content is removed, the previous versions will still follow these terms.
9. Ethical Use
You must use the content ethically and follow all relevant laws. This includes properly citing the original authors and not misusing the content.
10. Legal Compliance
You are responsible for making sure your use of the content follows the laws of your country. If you believe content violates your rights, please contact us.
11. Changes to Terms
These Terms and Conditions may be updated from time to time. Any changes will be posted on the Journal's website.
12. Contact Information
For questions about these Terms or for permission to use content commercially, please contact us at:
-
Email: eksplorium@brin.go.id
-
Website: https://ejournal.brin.go.id/eksplorium
Conclusion
By using the content from EKSPLORIUM - Buletin Pusat Pengembangan Bahan Galian Nuklir, you agree to follow these Terms and Conditions and the CC BY-NC-SA 4.0 International License.
References
[1] S.J. Suprapto, “Tinjauan Tentang Unsur Tanah Jarang”, Buletin Sumber Daya Geologi, Pusat Sumberdaya Geologi, Bandung, 1-11,2009.
[2] Sumarni, R. Prassanti R, K. Trinopiawan, Sumiarti, L.N. Hafni, “Penentuan Kondisi Pelarutan Residu dari Hasil Pelarutan Parsial Monasit Bangka”, Eksplorium, 32,115-124, 2011.
[3] M. Anggraini, “Proses Pemisahan Unsur Radioaktif dan Unsur Logam Tanah Jarang Pada Slag II Peleburan Timah”, Tesis Institut Teknologi Sepuluh November, Surabaya, 2016.
[4] I. Gaballah, E. Allain, M. Meyer-Joly, K. Malau, “A possible Methode for the Characterization of Amophous Slags : Recovery of Refractory Metal Oxide from Tin Slags”, Metall. Trans. B, 249–259, 1992
[5] C. Suhendar, “Penggunaan Tanah dalam Penurunan Konsentrasi Ion Ni2+ dan Cr6+ dari Limbah Elektroplating dengan Metode Jar Test”, Tesis Institut Pertanian Bogor, Bogor, 2012
[6] D.P. Marisi, “Optimalisasi Jenis Koagulan dalam Pengolahan Limbah Cair Bahan Pewarna Tekstil Melalui Proses Koagulasi dan Flokulasi”, Skripsi Universitas Sahid, Jakarta, 2012.
[7] Z. Salimin, “Proses Kimia Pengolahan Limbah Korosif Radioaktif dari Fabrikasi Bahan Bakar Nuklir”, Prosiding Pertemuan dan Presentasi Ilmiah, Yogyakarta, 1995.
[8] S. Putra, S. Rantjono, T. Arifiansyah, “ Optimasi Tawas dan Kapur untuk Koagulasi Air Keruh dengan PenandaI-131”, Prosiding Seminar Nasional V SDM Teknologi Nuklir; Yogyakarta, 2009.
[9] S. Yuliati, “Proses Koagulasi-Flokulasi pada Pengolahan Tersier Limbah Cair PT. Capsugel Indonesia”, Skripsi Institut Pertanian Bogor, Bogor, 2006.
[10] P.P.D.K. Wulan, Dianursanti, M. Gozan, W.A. Nugroho, “Optimasi Penggunaan Koagulan pada Pengolahan Air Limbah Batubara”, Prosiding Seminar Nasional Teknik Kimia Kejuangan, Yogyakarta, 2010.
[11] Z. Hamzah, T. N. T. M. Rosli, A. Saat and K. Wood, “An Assesment Of Natural Radionuclides In Water Of Langat River Estuary, Selangor”, Advancing Nuclear Research and Energy Development, Malaysia, 2014.
[12] S.W. Rachmawati, B. Iswanto, Winarni, “Pengaruh pH pada Proses Koagulasi dengan Koagulan Aluminium Sulfat dan Ferri Klorida”, Jurnal Teknologi Lingkungan, 5(2), 40-45, 2009.
[13] G. Alaerts, S.S. Santika, Metoda Penelitian Air. Surabaya: Usaha Nasional, 1987.
[14] I. A. Bhatti, M. A. Hayat, and M. Iqbal, “Assesment of Thorium In The Environment (A Review)”, Jurnal Chemistry Social Pakistan, Pakistan, 2012.
[15] Sunardi dan K. Wijayanti, “Pengolahan Limbah Besi Bengkel Bubut Menjadi Koagulan untuk Penjernihan Air”, Prosiding Seminar Nasional KPK II, Surakarta, 2010.
[16] W. Donald, Soundstrom, H.E. Klei, Wastewater Treatment. New Jersey: Prentice-Hall Int. Inc, 1979.