Pemisahan Itrium dengan Cara Ekstraksi Menggunakan Solven TOPO
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Abstract
Separation process of yttrium by extraction using TOPO solvents has been done. The purpose of this study is to find out the optimum condition of the variation effect of extractant concentration, stirring time, and acidity of the rare earth feed and to determine the distribution coefficient, separation factor, and extraction efficiency (%), using the liquid-liquid extraction method. The feed used were rare earth elements of xenotime sand. The extractant used in the research were TOPO (tri-n-octylphosphine oxide). Concentration of yttrium (Y), disprosium (Dy), and gadolinium (Gd) were determined using X-ray fluorescene spectrometer. Optimum conditions of the extraction process obtained from this study were: TOPO extractant concentration in kerosene 20%, stirring time 15 minutes, acidity of feed 0.5 M. Obtained value of distribution coefficient Y = 5.61; Dy = 2.06; Gd = 0.99. For extraction efficiency Y = 85.13%, Dy = 67.80%, Gd = 50.17% whereas separation factor Y-Dy = 2.7186 and Y-Gd = 5.6861.
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References
[1] Supardi, “Dijesti Bertingkat pada Pemisahan Konsentrat Y2O3 dari Pasir Senotim,” Universitas Gadjah Mada, 2002.
[2] A. N. Bintarti, Bambang, and M. V. Purwani, “Ekstraksi untuk Memisahkan Unsur-Unsur dalam Konsentrat Logam Tanah Jarang dari Pasir Senotim,” in Prosiding Pertemuan dan Presentasi Ilmiah Penelitian Dasar Ilmu Pengetahuan dan Teknologi Nuklir, P3TM-BATAN, 2002, pp. 257–261.
[3] Soebagio, E. Budiasih, M. S. Ibnu, H. R. Widarti, and Munzil, Kimia Analitik II. Malang: Universitas Negeri Malang, 2003.
[4] D. Biyantoro and M. V. Purwani, “Optimasi Pemisahan Zr-Hf dengan Cara Ekstraksi Memakai Solven TOPO,” J. Teknol. Bahan Nukl., vol. 9, no. 1, pp. 34–45, 2013.
[5] D. Biyantoro, “Ekstraksi Itrium dari Konsentrat Senotim Menggunakan D2EHPA - Dodekan,” in Prosiding PPI - PDIPTN, 2007, pp. 42–48.
[6] T. Handini, Bambang, and S. Sukmajaya, “Ekstraksi Y, Dy, Gd dari Konsentrat Itrium dengan Solven TBP dan D2EHPA,” J. Iptek Nukl. Ganendra, vol. 20, no. 1, pp. 49–55, 2017.
[7] R. Sulistyani, W. R. Pusparini, and D. Biyantoro, “Pemisahan Y, Dy, Gd Hasil Ekstraksi dari Konsentrat Itrium Menggunakan Kolom Penukar Ion,” in Prosiding PPI - PDIPTN, 2016, pp. 110–114.
[8] S. Prakash, Advanced Chemistry of Rare Elements. New Delhi: S. Chand Ltd, 1975.
[9] Sato, “The Extraction of Uranium (IV), Yttrium(III), and Lantanum(III) from Hydrochloric Solution by Acid Organophosphorus Cmpounds,” in Proceeding of the International Symposium on Actinide/ Lanthanide Separation, 1984.
[10] Suprihati, Purwoto, and Bambang, “Ekstraksi Konsentrat Logam Tanah Jarang dengan Topo Dalam HCl,” in Prosiding Seminar Penelitian dan Pengelolaan Perangkat Nuklir, 2008, pp. 221–224.
[11] M. V. Purwani, Suyanti, and A. W. Muhadi, “Ekstraksi Konsentrat Neodimium Memakai Asam di- 2 - etil Heksil Fosfat,” in Seminar Nasional IV SDM Teknologi Nuklir, 2008, pp. 439–447.
[12] J. R. Welty, C. E. Wicks, R. E. Wilson, and G. Rorrer, Dasar-Dasar Fenomena Transport, 4th ed. Jakarta: Erlangga, 2004.
