Adsorption of Phenol and Iron In Wastewater Using a Mixture of Active Carbon and Zeolite Modified with Chitosan
DOI:
https://doi.org/10.17146/jsmi.2022.24.1.6691Keywords:
Phenol, Fe, Activated Carbon, Zeolite, ChitosanAbstract
Phenol (C6H5OH) and iron (Fe2+) contained in electroplating industrial wastewater are toxic even at small concentrations. One of the effective methods to remove these compounds is adsorption because the method is easy and simple. Activated carbon and zeolite are types of adsorbents that are often used in wastewater treatment, but both types of adsorbents are not selective in certain chemicals. In this study, modification of zeolite and activated carbon with chitosan was carried out to adsorb waste containing phenol and Fe2+. The variations used were pH (7 and 9) and the adsorbent composition to study its effect on the adsorption of phenol in the presence of Fe2+. Adsorption was carried out in a bed with circulating waste for 2 hours. Feed at pH 9 with adsorbent mixed of zeolite-chitosan composite (Z-Ch) and activated carbon-chitosan composite (AC-Ch) in a ratio of 1:1 gave the optimal results. Under these conditions, 94% and 97% of phenol and Fe2+ were adsorbed, respectively.Downloads
References
Suntoyo and W. Sakinah. “Modelling of Phenol Contamination in Wonorejo Estuary, Indonesia.” IOP Conference
Series: Earth and Environmental Science, vol. 79, p. 012005, Jul. 2017.
C. R. Girish and V. R. Murty. “Mass Transfer Studies on Adsorption of Phenol from Wastewater Using Lantana
camara, Forest Waste.” International Journal of Chemical Engineering, vol. 2016, pp. 5809505, Feb. 2016.
L. Bandura, M. Franus, J. Madej, D. Kołodyńska, and Z. Hubicki. “Zeolites in Phenol Removal in the Presence of
Cu(II) Ions-Comparison of Sorption Properties after Chitosan Modification.” Materials (Basel), vol. 13, no. 3, Feb.
B. Xie, J. Qin, S. Wang, X. Li, H Sun, and W. Chen. “Adsorption of Phenol on Commercial Activated Carbons:
Modeling and Interpretation.” Int J Environ Res Public Health, vol. 17, no. 3, Jan. 2020.
M. Khalid, G. D. Joly, A. Renaud, and P. Magnoux. “Removal of Phenol from Water by Adsorption Using Zeolites.”
Industrial & Engineering Chemistry Research, vol. 43, no. 17, pp. 5275–5280, 2004.
F. A. Oluwadayo, M. A. A. Zaini, I. Misau, S. Abdulsalam, and U. El-Nafaty. “Adsorption dynamics of phenol by
crab shell chitosan.” Int. J. Chem. React. Eng., vol. 18, no. 8, p. 20200014, Jul. 2020.
A. Kumar and H. M. Jena.”Removal of methylene blue and phenol onto prepared activated carbon from Fox nutshell
by chemical activation in batch and fixedbed column.” Journal of Cleaner Production, vol. 137, pp 1246-1259,
U. Soni, J. Bajpai, S. K. Singh, and A. K. Bajpai. “Evaluation of chitosan-carbon based biocomposite for efficient
removal of phenols from aqueous solutions.” Journal of water process engineering, vol. 16, pp. 56–63, 2017.
S. Dalang and P. M. Tuah. “Removal of Phenol by Zeolite.” Transactions on Science and Technology, vol. 3, no. 1-
, pp. 107–113, 2016.
G. Issabayeva, S. Y. Hang, M. C. Wong, and M. K. Aroua. “A review on the adsorption of phenols from wastewater
onto diverse groups of adsorbents.” Reviews in Chemical Engineering, vol. 34, no. 6, pp. 855–873, 2018.
R. Rahmi, L. Lelifajri, and R. Nurfatimah. “Preparation of Polyethylene Glycol Diglycidyl Ether (PEDGE)
Crosslinked Chitosan/Activated Carbon Composite Film for Cd2+ Removal.” Carbohydrate Polymer, vol. 199, pp.
-505, Jul. 2018.
Air dan air limbah – Bagian 21 cara uji kadar fenol secara spektrofotometri, SNI 06-6989.21-2004.
Air dan air limbah – Bagian 4 cara uji besi (Fe) secara spektrofotometri serapan atom, SNI 6989.4-2009
J. K. Fatombi, E. A. Idohou, S. A. Osseni, I. Agani, D. Neumeyer, M. Verelst, R. Mauricot, and T. Aminou.
“Adsorption of Indigo Carmine from Aqueous Solution by Chitosan and Chitosan/Activated Carbon Composite:
Kinetics, Isotherms and Thermodynamics Studies.” Fibers and Polymers, vol. 20, no. 9, pp. 1820–1832, 2019.
L. Fereidooni, A. Abbaspourrad, and M. Enayati. “Electrolytic transesterification of waste frying oil using Na+
/zeolite– chitosan biocomposite for biodiesel production” Waste Management, vol 127, pp. 48-62, May. 2021.
A. O. Francis, M. A. A. Zaini, Z. A. Zakaria, I. M. Muhammad, S. Abdulsalam, and U. A. El-Nafaty. “Equilibrium
and kinetics of phenol adsorption by crab shell chitosan.” Particulate Science and Technology, vol. 39, no. 4, pp.
–426, 2021.
A. Płaza, D. Kołodyńska, P. Hałas, M. Gęca, M. Franus, and Z. Hubicki. “The zeolite modified by chitosan as an
adsorbent for environmental applications.” Adsorption Science & Technology, vol. 35, no. 9–10, pp. 834–844, 2017.
P. Wulan, Y. Kusumastuti, and A. Prasetya. “Removal of Fe (II) from Aqueous Solution by Chitosan Activated
Carbon Composite Beads.” Industrial Waste Management, vol. 898, pp. 3-8, 2020.
M. N. Rashed and P. N. Palanisamy. "Introductory Chapter: Adsorption and Ion Exchange Properties of Zeolites for
Treatment of Polluted Water." in Zeolites and Their Applications. London, United Kingdom: IntechOpen, 2018.
J. Yan and G. Quan. “Equilibrium And Kinetic Studies Of Phenol Sorption By Chitosan Coated Montmorillonite.”
J. Chil. Chem. Soc., vol. 54, no. 1, pp. 73–76, 2009.
Air dan air limbah – Bagian 71 cara uji kadar Cr6+ secara spektrofotometri, SNI 06-6989.71-2009.
R. Labied, O. Benturki, A. Y. E. Hamitouche, and A. Donnot. “Adsorption of hexavalent chromium by activated
carbon obtained from a waste lignocellulosic material (Ziziphus jujuba cores): Kinetic, equilibrium, and
thermodynamic study.” Adsorption Science & Technology, vol. 36, no. 3-4, pp. 1066-1099, 2018.
Downloads
Published
How to Cite
Issue
Section
License
This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
