Effect of Thermomechanical Treatment Combination on Electrochemical Behavior of Nickel Free-Stainless Steel Fe-10Mn-16Cr-3Mo
Keywords:
Nickel Free-Stainless steel, Fe-10Mn-16Cr-3Mo, Thermomechanical combination, CorrosionAbstract
Nickel-free stainless steel has emerged as an implant due to its excellent mechanical and corrosion properties. The toxic effect of Nickel ion released in the conventional SS316L need to be addressed. As one of austenitizing elements used as Nickel substitution, Nitrogen is an important alloying element to improve the strength and resistance to pitting susceptibility. In this research, the Nickel-free Fe-10Mn-16Cr-3Mo stainless steel has been developed. The effect of thermomechanical treatment consists of hot forging, hot rolling, cold rolling, and their combination followed by solution treatment on the electrochemical properties was further investigated. The corrosion resistance of Fe-10Mn-16Cr-3Mo was evaluated by the EIS and polarization test in Hank’s solution at 37℃. A ferrite-austenite duplex structure was identified by microstructural investigation, with indistinct intermetallic phase at homogenized sample. Meanwhile, fully recrystallized grains and twinning structures were formed at thermomechanical samples, indicating in dynamic recovery and dynamic recrystallization. Furthermore, the potentiodynamic parameters demonstrates the protective oxide in all samples. However, sample #5 shows a lower current density, around 0.184 µA/cm2, compared to other samples, indicating more protective passive film. In addition, the corrosion potential of sample #5, around 198 mV leading to higher corrosion resistance up to 0.02894 mmpy.
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References
K. A. Pacheco. “Allergy to Surgical Implants.” Clin. Rev. Allergy Immunol., vol. 56, no. 1, pp. 72–85, Sep. 2019.
K. Yang, Y. Ren, and P. Wan. “High nitrogen nickel-free austenitic stainless steel: A promising coronary stent
material.” Sci. China Technol. Sci., vol. 55, no. 2, pp. 329–340, Feb. 2012.
K. Yang and Y. Ren. “Nickel-free austenitic stainless steels for medical applications.” Sci. Technol. Adv. Mater.,
vol. 11, no. 1, p. 014105, Feb. 2010.
C. A. Baumann and B. D. Crist. “Nickel allergy to orthopaedic implants: A review and case series.” J. Clin.
Orthop. Trauma, vol. 11, pp. S596–S603, Feb. 2020.
M. Li et al. “Study of biocompatibility of medical grade high nitrogen nickel-free austenitic stainless steel in
vitro.” Mater. Sci. Eng. C, vol. 43, pp. 641–648, Oct. 2014.
M. Talha, C. K. Behera, and O. P. Sinha. “A review on nickel-free nitrogen containing austenitic stainless steels
for biomedical applications.” Mater. Sci. Eng. C, vol. 33, no. 7, pp. 3563–3575, Jun. 2013.
L. Patnaik, S. R. Maity, and S. Kumar. “Status of nickel free stainless steel in biomedical field: A review of last
years and what else can be done,” Mater. Today Proc., vol. 26, no. 2, pp. 638–643, 2019.
Y. Wang, Y. Wang, and Z. Wang. “Enhancing yield strength of high nitrogen austenitic stainless steel.” J. Constr.
Steel Res., vol. 187, no. May, p. 106927, Dec. 2021.
M. Talha, C. K. Behera, and O. P. Sinha, “Effect of nitrogen and cold working on structural and mechanical
behavior of Ni-free nitrogen containing austenitic stainless steels for biomedical applications,” Mater. Sci. Eng.
C, vol. 47, pp. 196–203, Feb. 2015.
J. Li et al. “Enhancing Pitting Corrosion Resistance of Severely Cold-Worked High Nitrogen Austenitic Stainless
Steel by Nitric Acid Passivation.” J. Electrochem. Soc., vol. 166, no. 13, pp. C365–C374, 2019.
B. B. Singh et al. “A Comparative Study on the Ballistic Performance and Failure Mechanisms of High-Nitrogen
Steel and RHA Steel Against Tungsten Heavy Alloy Penetrators.” J. Dyn. Behav. Mater., vol. 7, no. 1, pp. 60–
, 2021.
J. Lal, S. Kumar, and N. C. S. Srinivas. “Effect of Preliminary Cold Working on High-Temperature Tensile
Behavior of Nickel-Free High-Nitrogen Austenitic Steel.” Met. Sci. Heat Treat., vol. 61, no. 7–8, pp. 478–481,
L. M. Kaputkina, M. G. Medvedev, V. G. Prokoshkina, I. V. Smarygina, and A. G. Svyazhin. “Influence of
alloying by nitrogen on the strength and austenite stability of X18H10 steel.” Steel Transl., vol. 44, no. 7, pp.
–508, 2014.
N. Fuertes and R. Pettersson. “Effect of cold rolling on microstructure, corrosion and electrochemical response
of the lean duplex stainless steel LDX 2101® by a correlative EBSD–SKPFM investigation.” Mater. Corros.,
vol. 71, no. 7, p. 1052–1065, 2020.
F. Ruffini et al. “Modelling approach to support design of new high nitrogen austenitic steel for wind turbines
components.” Wind Eng., vol. 40, no. 5, pp. 419–425, Aug. 2016.
R. M. Santos, D. G. Rodrigues, M. L. Dias Santos, and D. B. Santos. “Martensite reversion and strain hardening
of a 2304 lean duplex stainless steel subjected to cold rolling and isochronous annealing at low temperatures.” J.
Mater. Res. Technol., vol. 16, pp. 168–186, 2022.
A. D. Halimi, Sulistijono, and M. I. P. Hidayat. “Microstructural characterization of super duplex stainless steel
UNS S32760 after heat treatment in different cooling media,” in AIP Conference Proceedings, 2020, vol. 2296,
no. April 2021, p. 020077.
I. G. S. Sandhu, R. D. Simari, D. R. Holmes, M. D. D. Daescu, and A. P. Parakka. “Medical devices including
duplex stainless steel." U.S. Patent Application No. US 2013/0211537 A1, Aug. 15, 2013.
G. G. B. Maria, C. A. D. Pedroso, D. G. Rodrigues, and D. B. Santos. “Strain-Induced Martensite and Reverse
Transformation in 2304 Lean Duplex Stainless Steel and its Influence on Mechanical Behavior.” Steel Res. Int.,
vol. 90, no. 3, pp. 1–11, 2019.
V. S. A. Challa, X. L. Wan, M. C. Somani, L. P. Karjalainen, and R. D. K. Misra. “Strain hardening behavior of
phase reversion-induced nanograined/ultrafine-grained (NG/UFG) austenitic stainless steel and relationship with
grain size and deformation mechanism.” Mater. Sci. Eng. A, vol. 613, pp. 60–70, 2014.
R. Badji, B. Cheniti, C. Kahloun, T. Chauveau, M. Hadji, and B. Bacroix. “Microstructure, mechanical behavior,
and crystallographic texture in a hot forged dual-phase stainless steel.” Int. J. Adv. Manuf. Technol., vol. 116, no.
–4, pp. 1115–1132, 2021.
D. M. Bastidas, J. Ress, J. Bosch, and U. Martin. “Corrosion mechanisms of high-mn twinning-induced plasticity
(Twip) steels: A critical review.” Metals, vol. 11, no. 2. pp. 1–45, 2021.
V. Kumar, R. K. Gupta, and G. Das. “Influence of Forging and Annealing on the Microstructure and Corrosion
Behavior of Austenitic Stainless Steel.” J. Inst. Eng. Ser. D, vol. 101, no. 1, pp. 105–109, 2020.
E. Rahimi, A. Kosari, S. Hosseinpour, A. Davoodi, H. Zandbergen, and J. M. C. Mol. “Characterization of the
passive layer on ferrite and austenite phases of super duplex stainless steel.” Appl. Surf. Sci., vol. 496, no. May,
p. 143634, 2019.
H. Zhang et al. “Different corrosion behaviors between α and β phases of Ti6Al4V in fluoride-containing
solutions: Influence of alloying element Al.” Corros. Sci., vol. 169, no. November 2019, 2020.
A. Yilmaz, X. Li, S. Pletincx, T. Hauffman, J. Sietsma, and Y. Gonzalez-Garcia. “Passive Film Properties of
Martensitic Steels in Alkaline Environment: Influence of the Prior Austenite Grain Size.” Metals (Basel)., vol.
, no. 2, Feb. 2022.
M. Rohmah, F. M. Ridlo, Y. N. Thaha, P. A. Paristiawan, and N. R. Hakim. “e.” Eng. Appl. Sci. Res., vol. 49, no.
, pp. 681–687, 2022.
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