THE INFLUENCE OF COMPOSITION OF CNT (CARBON NANOTUBE) ON THE PHYSICAL PROPERTIES OF BIOPLASTIC MADE FROM CASSAVA STARCH
DOI:
https://doi.org/10.17146/jsmi.2019.20.4.5514Keywords:
BioplasticAbstract
Bioplastics are starch-based polymers that are easily degraded by microorganisms, so they can be used as an alternative to the use of conventional plastics. In this research, bioplastics made from cassava starch was made using glycerol as plasticizer and used MWCNTs (Multi-Wall CNTs) type CNT as reinforcement with variations in the composition of 0%, 1%, 2%, and 3%. Bioplastics are made with a dry method (dry blending) with stages of pre-mixing, mixing, hot press and cold press. Characteristics of bioplastic starch/CNT include tensile strength, biodegradation and morphological. The test results show that the addition of CNT composition affects the mechanical properties of bioplastics. The optimum value of tensile strength occurred in the addition of 2% CNT at 13.52 MPa. Biodegradable test results using the Aspergillus niger mushroom prove that bioplastic starch/CNT can be degraded well. The results of morphological characteristics in the form of SEM results showed that 3% bioplastic starch / CNT had cracks and resulted in decreased tensile strength. FTIR test results indicate the presence of a new functional group C≡C because of the addition of CNT.
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References
. J.R. Jambeck, R. Geyer, C. Wilcox, T.R. Siegler, M.
Perryman, A. Andrady, R. Narayan, H.K. Lavender.
“ Plastic Waste Inputs from Land into the Ocean.”
Science 347, 768, 2015.
. H. Suryanto, P. T. Hutomo, R. Wanjaya, and P.
Puspitasari. “ The Structure Bioplastic from
Cassava Starch with Nanoclay Reinforcement.” AIP
Int. Proceding Int. Mech. Eng. Educ., vol 30027,
pp-1-4, 2016
. A.H.D Abdullah, S. Pujiraharti, M. Karina, O.D.
Putri, R.H Fauziyyah. “Fabrication and
Characterization of Sweet Potato Starch-based
Bioplastics Plasticized with Glycerol.” Journal
Biological Science, 57-64, 2019
. Melani Ani Netty Herawati, A. Fajri Kurniawan. “
Bioplastik Pati Umbi Talas melalui Proses Melt
Intercalation.” Distilasi, Vol.2 No.2 September, Hal
-67, 2017
. Rifaldi Anugrah, Irdoni Hs, Bahruddin. “ Sifat dan
Morfologi Bioplastik Berbasis Pati Sagu dengan
Penambahan Filler Clay dan Plasticizer Gliserol.”
Jom FTEKNIK Volume 4 No.1 Februari, 2017
. Santana R.F, R.C.F Bonomo, O.R.R Gandolf, L.B.
Rodrigues, and L.S. Santos et.al. “ Characterization
of Starch-based Bioplastic from Jackfruit Seed
Plasticizer with Glycerol.” J. Food Sci. Technol.,
: 278-286, 2018
. Isroi, A. Cifriadi, T. Panji, N. A. Wibowo, and K.
Syamsu. “Bioplastic Production from Cellulose of
Oil Palm Empty Fruit Bunch.” IOP Conf. Ser. Earth
Environ. Sci., vol. 65, no. 1, 2017.
. Iijima S .” Helical Microtubulec of Grafhitic Carbon.
Nature.” 1991
. William D. Callister JR.”Material Science and
Engineering An Introduction, Fourth Edition .”.
John Wiley & Sons Inc, 1997.
. Barai P, Weng G J. “A Theory of Plasticity for
Carbon Nanotube Reinforced Composite.”
International Journal of Plasticity 27 : 539-559, 2011
. Hermawan Judawisastra, Christian Harito, Akbar
H. Dawam Abdullah.” Effect of Amide
Functionalization and Precuring on Tensile
Properties of MWCNT/Epoxy Nanocomposite.”
Journal of Macromolecular Symposia, Volume 35/
issue 1, p 88-95, 2015
. Porras M A, Cubitto M A, Villar M A. “ A new way
of quantifying the production of
poly(hydroxyalkanoate)s using FTIR.” J Chem
Tech Biotechnol. 2015
. Pavia D L, Lampman G M, Kriz G S. “Introduction
to Spectroscopy.” (Philadelphia: Thomson Brooks/
Cole) p 23, 2001
. Qu P, Gao Y, Wu G F, Zhang L P. “BioResouces 5.”
-1823, 2010
. Darni, dkk.” Produksi Bioplastik dari Sorgum dan
Selulosa Secara Termoplastik.” Jurnal Rekayasa
Kimia Dan Lingkungan, 10 (2), 2014
. Prolongo S G, Gude M R, Urena A. “Improving the
Flexural and Thermomechanical Properties of
Amino-Functionalized Carbon Nanotube/Epoxy
Composite by Using a Pre-Curing Treatment.”
Composite Science and Technology 71 : 765-771,
. A. Septiosari, Latifah, and Kusumastuti Ella.
“Pembuatan Dan Karakterisasi Biopl Astik Limbah
Biji Mangga Dengan Penambahan Selulosa Dan
Gliserol.” Chem. Sci., vol. 3, no. 2252, pp. 1–6, 2014.
. R. Harnist and Y. Darni. “Penentuan Kondisi
Optimum Konsentrasi Plasticizer Pada Sintesa
Plastik Biodegradable Berbahan Dasar Pati
Sorgum,” in Seminar Nasional Sains dan Teknologi,
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