Li ION CONDUCTING POLYMER BASED ON POLYVINYLIDENE FLUORIDE AND Li TRIFLATE

Authors

  • Evi Yulianti Center for Technology of Nuclear Industry Material (PTBIN)-BATAN, Kawasan Puspiptek, Serpong 15314, Tangerang Selatan
  • Sudaryanto Center for Technology of Nuclear Industry Material (PTBIN)-BATAN, Kawasan Puspiptek, Serpong 15314, Tangerang Selatan
  • Heri Jodi Center for Technology of Nuclear Industry Material (PTBIN)-BATAN, Kawasan Puspiptek, Serpong 15314, Tangerang Selatan
  • Deswita Center for Technology of Nuclear Industry Material (PTBIN)-BATAN, Kawasan Puspiptek, Serpong 15314, Tangerang Selatan
  • Mashadi Center for Technology of Nuclear Industry Material (PTBIN)-BATAN, Kawasan Puspiptek, Serpong 15314, Tangerang Selatan

Keywords:

Polyvinylidene Fluoride, Lithium triflate, Ionic conductivity

Abstract

Li ION CONDUCTING POLYMER BASED ON POLYVINYLIDENE FLUORIDE AND Li TRIFLATE. A Series of polymer electrolyte based on Polyvinylidene Fluoride (PVDF) for solid state rechargeable lithium battery has been prepared by solution casting technique. Lithium triflate salt was used as filler with various compositions. Bulk nature and surface morphology of the polymer electrolytes were studied by X-Ray Diffractometer (XRD) and Scanning Electron Microscope (SEM), respectively. The thermal properties of polymer and salt were confirmed by Differential Scanning Calorimeter (DSC). The electrical properties of electrolyte polymer membrane were studied by using impedance spectrometer. It was found that the highest ionic conductivity was obtained for PVDF + Li Triflate 10%(w/w) which is 4.5411 x 10-3 S/cm. It was also found that there was peak of each composition in the loss tangent suggests the presence of relaxing dipoles in the polymer electrolyte films. The peak shifts towards higher frequency side suggesting the speed up of the relaxation time.

Downloads

Download data is not yet available.

References

. C. POLO FONSECA, S. NEVES, Journal of Power Sources, 159 (2006) 712-716

. E.KARTINI,T.Y.S. PANCAPUTRA,I.KUNTORO, T. SAKUMA, K. BASAR, O. KAMISHIMA and J. KAWAMURA, Journal Physical Society, 79 Suppl.A. (2010) 54-58

. E. MORALES, J.L. ACOSTA, Solid State Ionics, 96 (1997) 99

. C.J. LEO, G.V. SUBBARAO, B.V.R CHOWDARI, Solid State Ionics, 148 (2002) 159

. P.P. CHU, M.J. REDDY, H.M. KAO, Solid State Ionics, 156 (2003) 141

. M.A.K.L. DISSAYANAKE, L.R.A.K BANDARA, R.S.P. BOKALAWALA, P.A.R.D JAYATHILAKA, O.A. ILEPERUMA, S. SOMASUNDARAM, Materials Research Bulletin, 37(2002) 867-874

. O. BOHNKE, G. FRAND, M. REZRAZI, Solid State Ionics, 66 (1993) 97

. C. POLO FONSECA, F. CAVALCANTE JR, F.A. AMARAL, C.A. ZANI SOUZA and S. NEVES,Int. J. Electrochem. Sci., 2 (2007) 52-63

. N.H. IDRIS, S.R. MAJID, A.S.A. KHIAR, M.F. HASSAN,A.K.AROF, Ionics, 11 (2005) 375-381

. S.R. MAJID, A.K. AROF, Physica B, 355 (2005) 78-82

. A.S.A. KHIAR, R. PUTEH,A.K.AROF, Physica B, 373 (2006) 23-27

. F. BOUDIN, X. ANDRIEU, C. JEHOULET, I.I. OLSEN, J. Power Sources, 81-81 (1999) 804

. S.RAJENDRAN,O.MAHENDRAN, O.KANNAN, Materials Chemistry and Physics, 74 (2002) 52-57

. G. BAUDUIN, B. BOUTEVIN, P. GRAMAIN, A. MALINOVA, Europe Polymer Journal, 35 (1999)285

. C.Y. CHIANG,Y.J. SHEN, M.J. REDDY, P.P. CHU, Journal of Power Sources, 123 (2003) 222-229

. K. XU, Chemical Review, 104 (2004) 4303-4417

. D.K. PRADHAN, R.N.P. CHOUDARY, B.K. SAMANTARAY, Int. J. Electrochem Sci., 3 (2000) 597-608

Downloads

Published

21-10-2026

How to Cite

Evi Yulianti, Sudaryanto, Heri Jodi, Deswita, & Mashadi. (2026). Li ION CONDUCTING POLYMER BASED ON POLYVINYLIDENE FLUORIDE AND Li TRIFLATE. Jurnal Sains Materi Indonesia, 15(1), 24–28. Retrieved from https://ejournal.brin.go.id/jsmi/article/view/6164

Issue

Vol. 15 No. 1 (2013): Jurnal Sains dan Materi Indonesia

Section

Articles

License

Creative Commons License

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.