The Influence of Anodizing Electrolyte Concentration on Ni-P Deposition on Anodic Aluminum Oxide (AAO)
DOI:
https://doi.org/10.55981/jsmi.2025.9708Keywords:
Electroless Deposition, Ni-P, Anodic Aluminum Oxide, Aluminum AlloyAbstract
Aluminum alloys suffer from deficiencies in surface performance due to insufficient resistance to corrosion and mechanical qualities in harsh environments. Therefore, it is crucial to apply a protective surface modification during the manufacturing process of the aluminum component. The electroless deposited Ni-P shows great potential as a protective coating due to its simple manufacturing process and outstanding performance. This study investigates the effect of oxalic acid concentration in the anodizing process on electroless Ni-P coating. In this study, Anodic Aluminum Oxide (AAO) is formed by an anodizing process on 0.3,0.5, and 0.7 oxalic acids prior to Ni-P electroless deposition. The resulting Ni-P layer has a nodular-like morphology with a size in the order of 0.5 m or less. Moreover, the AAO surface is covered by a thin and tightly formed layer of nickel particles. The EDX analysis shows the oxygen percentage falls by up to 70% after Ni deposition in all anodizing parameters, as compared to the anodized specimens alone. In addition, the nickel content gradually decreases as the concentration of oxalic acid increases from 0.3 M to 0.7 M.
Downloads
References
[1] Y. Wang et al., “Influence of pretreatments on physicochemical properties of Ni-P coatings electrodeposited on aluminum alloy,” Mater Des, vol. 197, p. 109233, 2021, doi: https://doi.org/10.1016/j.matdes.2020.109233.
[2] M. Abedini and S. Hanke, “Improving the wear resistance of aluminum by a nickel-filled anodized porous alumina layer,” Wear, vol. 522, p. 204858, 2023, doi: https://doi.org/10.1016/j.wear.2023.204858.
[3] V. N. Kale, J. Rajesh, T. Maiyalagan, C. W. Lee, and R. M. Gnanamuthu, “Fabrication of Ni–Mg–Ag alloy electrodeposited material on the aluminium surface using anodizing technique and their enhanced corrosion resistance for engineering application,” Mater Chem Phys, vol. 282, p. 125900, 2022, doi: https://doi.org/10.1016/j.matchemphys.2022.125900.
[4] Z. Yin and F. Chen, “Effect of nickel immersion pretreatment on the corrosion performance of electroless deposited Ni–P alloys on aluminum,” Surf Coat Technol, vol. 228, pp. 34–40, 2013, doi: https://doi.org/10.1016/j.surfcoat.2013.04.001.
[5] F. Davoodi, F. Ashrafizadeh, M. Atapour, E. Akbari-Kharaji, and R. Mokhtari, “Anticorrosion performance of TiN coating with electroless nickel-phosphorus interlayer on Al 6061 alloy,” Mater Chem Phys, vol. 296, p. 127170, 2023, doi: https://doi.org/10.1016/j.matchemphys.2022.127170.
[6] M. Sundararajan, M. Devarajan, and M. Jaafar, “Electroless NiB sealing on nanoporous anodic aluminum oxide pattern: deposition and evaluation of its characteristic properties,” Journal of Materials Research and Technology, vol. 19, pp. 4504–4516, Jul. 2022, doi: 10.1016/j.jmrt.2022.06.169.
[7] A. S. Kumar, K. Mohanam, G. Venkatachalam, S. Karthikeyan, and S. Narayanan, “Influence of Nickel Coating on Flexural and Dynamic Behaviour of Aluminium,” Procedia Eng, vol. 97, pp. 1368–1378, 2014, doi: https://doi.org/10.1016/j.proeng.2014.12.418.
[8] E. Khan, C. F. Oduoza, and T. Pearson, “Surface characterization of zincated aluminium and selected alloys at the early stage of the autocatalytic electroless nickel immersion process,” J Appl Electrochem, vol. 37, no. 11, pp. 1375–1381, 2007, doi: 10.1007/s10800-007-9397-y.
[9] P. Sahoo and S. K. Das, “Tribology of electroless nickel coatings – A review,” Mater Des, vol. 32, no. 4, pp. 1760–1775, 2011, doi: https://doi.org/10.1016/j.matdes.2010.11.013.
[10] M. Gholizadeh-Gheshlaghi, D. Seifzadeh, P. Shoghi, and A. Habibi-Yangjeh, “Electroless Ni-P/nano-WO3 coating and its mechanical and corrosion protection properties,” J Alloys Compd, vol. 769, pp. 149–160, 2018, doi: https://doi.org/10.1016/j.jallcom.2018.07.304.
[11] J. P. Davim, S. Das, and P. Sahoo, “Roughness Optimization of Electroless Ni-B Coatings Using Taguchi Method,” 2013, pp. 302–319. doi: 10.4018/978-1-4666-1867-1.ch018.
[12] S. Kalyan Das and P. Sahoo, “Optimisation of tribological performance of electroless Ni–B coating using Taguchi method and grey relational analysis,” Tribology - Materials, Surfaces & Interfaces, vol. 5, no. 1, pp. 16–24, Mar. 2011, doi: 10.1179/1751584X10Y.0000000004.
[13] S. Das and P. Sahoo, “Wear Performance Optimization of Electroless Ni-B Coating Using Taguchi Design of Experiments,” Tribology in Industry, vol. 32, Dec. 2010.
[14] P. Sahoo and P. Gadhari, “Optimization of Friction and Wear Properties of Electroless Ni-P-Al2O3 Composite Coatings,” International Journal of Surface Engineering and Interdisciplinary Materials Science, vol. 2, pp. 34–52, Jun. 2014, doi: 10.4018/IJSEIMS.2014070103.
[15] V. Vitry, J. Hastir, A. Mégret, S. Yazdani, M. Yunacti, and L. Bonin, “Recent advances in electroless nickel-boron coatings,” Surf Coat Technol, vol. 429, p. 127937, 2022, doi: https://doi.org/10.1016/j.surfcoat.2021.127937.
[16] D. Xu, H. Zhao, and C. Zhen, “Preparation of transparent anodic aluminum oxide films and their structural characteristics under thermal shock,” Microporous and Mesoporous Materials, vol. 363, p. 112849, 2024, doi: https://doi.org/10.1016/j.micromeso.2023.112849.
[17] A. K. Eessaa and A. M. El-Shamy, “Review on fabrication, characterization, and applications of porous anodic aluminum oxide films with tunable pore sizes for emerging technologies,” Microelectron Eng, vol. 279, p. 112061, 2023, doi: https://doi.org/10.1016/j.mee.2023.112061.
[18] L. Lerner, “Hard anodising of aerospace aluminium alloys,” Transactions of the Institute of Metal Finishing, vol. 88, pp. 21–24, Jan. 2010, doi: 10.1179/174591909X12614823458038.
[19] L. R. Krishna, Y. Madhavi, P. S. Babu, D. S. Rao, and G. Padmanabham, “Strategies for corrosion protection of non-ferrous metals and alloys through surface engineering,” Mater Today Proc, vol. 15, pp. 145–154, 2019, doi: https://doi.org/10.1016/j.matpr.2019.05.037
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2025 Vika Rizkia, Iwan Susanto, Belyamin, Vina Nanda Garjati, Ade Utami Hapsari, Jarot Raharjo, Damisih, Retna Deca Pravitasari

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.





