Electrochemical Investigation of Ethylene Glycol as Corrosion Inhibitor of Al 5052

Authors

  • I. Habibi Universitas Muhammadiyah Magelang
  • Arini Nikitasari Research Center for Metallurgy, National Research and Innovation Agency
  • Saifudin Universitas Muhammadiyah Magelang
  • Rahayu Kusumastuti National Research and Innovation Agency
  • Siti Musabikha National Research and Innovation Agency
  • Siska Prifiharni National Research and Innovation Agency
  • Januar Irawan National Research and Innovation Agency
  • Gadang Priyotomo National Research and Innovation Agency
  • Rini Riastuti Universitas Indonesia

DOI:

https://doi.org/10.55981/jsmi.2024.4398

Keywords:

Al 5052, Coolant, Electric car, Electrochemical, Ethylene Glycol

Abstract

Nowadays, electric cars use Al 5052 in the cooling pad of the battery coolant system. Corrosion behavior study of Al 5052 by coolant is essential in the automotive industry. Ethylene glycol is the main compound of the battery coolant system that can inhibit the corrosion process of aluminum alloys. The corrosion inhibition performance of ethylene glycol (EG) for Al 5052 surface in 3.5% NaCl solution has been studied using electrochemical measurements such as potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) in various concentrations of EG up to 50% and a temperature range from 30oC to 60oC. Based on results, EG can inhibit the corrosion process of Al 5052. The corrosion rate (CR) of coolant containing EG decreases with increasing that concentration in various temperatures, and the CR of the coolant rises with the increased temperatures. The inhibition efficiency of coolant boosts with the increase in EG concentration in each operational temperature and the highest up to 75% at 60oC with 50% of EG concentration.

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References

S. Vitta, “Electric cars – Assessment of ‘green’ nature vis-à-vis conventional fuel driven cars,” Sustain. Mater. Technol., vol. 30, no. September, p. e00339, 2021, doi: 10.1016/j.susmat.2021.e00339.

M. Liu et al., “CO2 emissions from electric flying cars: Impacts from battery specific energy and grid emission factor,” eTransportation, vol. 13, p. 100189, 2022, doi: 10.1016/j.etran.2022.100189.

M. Lebrini, F. Bentiss, N. Chihib, C. Jama, J. Pierre, and M. Lagrenée, “Polyphosphate derivatives of guanidine and urea copolymer : Inhibiting corrosion effect of armco iron in acid solution and antibacterial activity,” Corros. Sci., vol. 50, no. 10, pp. 2914–2918, 2008, doi: 10.1016/j.corsci.2008.07.003.

M. R. Kærn, A. Modi, J. K. Jensen, and J. G. Andreasen, “An assessment of in-tube flow boiling correlations for ammonia – water mixtures and their influence on heat exchanger size,” Appl. Therm. Eng., vol. 93, pp. 623–638, 2016, doi: 10.1016/j.applthermaleng.2015.09.106.

S. Bharti, V. Dutta, S. Sharma, and N. D. Ghetiya, “Investigating the effect of tool speed on the mechanical properties of Al5052 processed by friction stir processing,” Mater. Today Proc., vol. 33, no. xxxx, pp. 1605–1609, 2019, doi: 10.1016/j.matpr.2020.05.547.

A. P. Markopoulos, E. L. Papazoglou, P. Svarnias, and P. Karmiris-Obratanski, “An experimental investigation of machining aluminum alloy Al5052 with EDM,” Procedia Manuf., vol. 41, pp. 787–794, 2019, doi: 10.1016/j.promfg.2019.09.071.

H. Ju, S. Liu, W. Zhang, Y. Yang, and J. Duan, “Investigation of pitting corrosion and hydrogen evolution of aluminum and AA2024 alloy by simultaneous electrochemical measurements and imaging,” Electrochem. commun., vol. 132, p. 107135, 2021, doi: 10.1016/j.elecom.2021.107135.

M. K. Awad, M. S. Metwally, S. A. Soliman, A. A. El-Zomrawy, and M. A. bedair, “Experimental and quantum chemical studies of the effect of poly ethylene glycol as corrosion inhibitors of aluminum surface,” J. Ind. Eng. Chem., vol. 20, no. 3, pp. 796–808, 2014, doi: 10.1016/j.jiec.2013.06.009.

A. M. Fekry and M. Z. Fatayerji, “Electrochemical corrosion behavior of AZ91D alloy in ethylene glycol,” Electrochim. Acta, vol. 54, no. 26, pp. 6522–6528, 2009, doi: 10.1016/j.electacta.2009.06.025.

X. Chen, W. Tian, S. Li, M. Yu, and J. Liu, “Effect of temperature on corrosion behavior of 3003 aluminum alloy in ethylene glycol–water solution,” Chinese J. Aeronaut., vol. 29, no. 4, pp. 1142–1150, 2016, doi: 10.1016/j.cja.2015.12.017.

G. A. Rassoul, D. M. El-Din Kassim, and B. H. EsSebbagh, “corrosion Inhibition of Aluminum Alloy in 50% Ethylene GlYcol Solution,” IICPT lraqi Joumal Chcmical atrd Pearoleum Engir.cring lraoi Journalof Chem. Pet. Eng., vol. 8, no. 3, pp. 53–59, 2007, [Online]. Available: https://www.iasj.net/iasj?func=fulltext&aId=24689.

G. Priyotomo and I. N. Gede Putrayasa Astawa, “THE EFFECT OF Fe-ENRICH PHASE ON THE PITTING CORROSION RESISTANCE OF Al ALLOY IN VARIOUS NEUTRAL SODIUM CHLORIDE SOLUTIONS,” Int. J. Sci. Eng., vol. 7, no. 2, pp. 143–149, 2014, doi: 10.12777/ijse.7.2.143-149.

H. Medhashree and A. N. Shetty, “Electrochemical corrosion study of Mg-Al-Zn-Mn alloy in aqueous ethylene glycol containing chloride ions,” J. Mater. Res. Technol., vol. 6, no. 1, pp. 40–49, 2017, doi: 10.1016/j.jmrt.2016.04.003.

A. Nikitasari, Sundjono, G. Priyotomo, and A. Royani, “Sargassum seaweed extract as a novel green corrosion inhibitor for API-5L carbon steel,” Int. J. Corros. Scale Inhib., vol. 10, no. 4, pp. 1689–1699, 2021, doi: 10.17675/2305-6894-2021-10-4-20.

A. Nikitasari, G. Priyotomo, A. Royani, and S. Sundjono, “Exploration of Eucheuma Seaweed Algae Extract as a Novel Green Corrosion Inhibitor for API 5L Carbon Steel in Hydrochlorid Acid Medium,” vol. 35, no. 03, pp. 596–603, 2022, doi: 10.5829/ije.2022.35.06c.13.

X. Zhang et al., “Corrosion behaviors of 5A06 aluminum alloy in ethylene glycol,” Int. J. Electrochem. Sci., vol. 13, no. 11, pp. 10470–10479, 2018, doi: 10.20964/2018.11.64.

I. S. Eis, A. Nikitasari, E. Mabruri, and R. Riastuti, “Engineering and Applied Science Research Corrosion behavior of CA6NM in simulated geothermal brine highlighted by Electrochemical,” vol. 48, no. 4, pp. 359–367, 2021, doi: 10.14456/easr.2021.38.

M. Yeganeh, N. Asadi, M. Omidi, and M. Mahdavian, “Progress in Organic Coatings An investigation on the corrosion behavior of the epoxy coating embedded with mesoporous silica nanocontainer loaded by sulfamethazine inhibitor,” Prog. Org. Coatings, vol. 128, no. December 2018, pp. 75–81, 2019, doi: 10.1016/j.porgcoat.2018.12.022.

M. Mehdipour, B. Ramezanzadeh, and S. Y. Arman, “Electrochemical noise investigation of Aloe plant extract as green inhibitor on the corrosion of stainless steel in 1M H2SO4,” J. Ind. Eng. Chem., vol. 21, pp. 318–327, 2015, doi: 10.1016/j.jiec.2014.02.041.

A. H. El-Askalany, S. I. Mostafa, K. Shalabi, A. M. Eid, and S. Shaaban, “Novel tetrazole-based symmetrical diselenides as corrosion inhibitors for N80 carbon steel in 1 M HCl solutions: Experimental and theoretical studies,” J. Mol. Liq., vol. 223, pp. 497–508, 2016, doi: 10.1016/j.molliq.2016.08.088.

A. Kr??likowski and J. Kuziak, “Impedance study on calcium nitrite as a penetrating corrosion inhibitor for steel in concrete,” Electrochim. Acta, vol. 56, no. 23, pp. 7845–7853, 2011, doi: 10.1016/j.electacta.2011.01.069.

A. Singh, K. R. Ansari, D. S. Chauhan, M. A. Quraishi, and S. Kaya, “Anti-corrosion investigation of pyrimidine derivatives as green and sustainable corrosion inhibitor for N80 steel in highly corrosive environment: Experimental and AFM/XPS study,” Sustain. Chem. Pharm., vol. 16, no. April, 2020, doi: 10.1016/j.scp.2020.100257.

T. Shahrabi, M. Hosseini, M. Ghorbani, and M. Arshadi, “Synergistic Influence of Benzoate Ions on Inhibition of Corrosion of Mild Steel in 0.5M Sulfuric Acid By Benzotriazole,” Int. J. Eng., vol. 16, no. 3, pp. 255–264, 2003.

R. Liu, L. Jiang, J. Xu, C. Xiong, and Z. Song, “Influence of carbonation on chloride-induced reinforcement corrosion in simulated concrete pore solutions,” Constr. Build. Mater., vol. 56, pp. 16–20, 2014, doi: 10.1016/j.conbuildmat.2014.01.030.

M. Goyal et al., “Isopentyltriphenylphosphonium bromideionic liquid as a newly effective corrosion inhibitor on metal-electrolyte interface in acidic medium: Experimental, surface morphological (SEM-EDX & AFM) and computational analysis,” J. Mol. Liq., vol. 316, p. 113838, 2020, doi: 10.1016/j.molliq.2020.113838.

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Published

06-08-2024

How to Cite

Habibi, Nikitasari, A., Saifudin, Kusumastuti, Musabikha, Prifiharni, … Riastuti. (2024). Electrochemical Investigation of Ethylene Glycol as Corrosion Inhibitor of Al 5052. Jurnal Sains Materi Indonesia, 26(1), 53–64. https://doi.org/10.55981/jsmi.2024.4398