KARAKTERISTIK DAN POTENSI PEMANFAATAN ASAP CAIR KAYU TREMA, NANI, MERBAU, MATOA, DAN KAYU MALAS
Main Article Content
Abstract
Wood is potential biomass with various benefits such as is utilizing them for liquid smoke raw material. Consequently,
research on liquid smoke by pyrolysis should be conducted intensively to gain necessary information on the active content
and utilization of the liquid smoke. This research is aimed to determine characteristics and potential utilization of
liquid smoke made from trema, nani, merbau, matoa and malas wood. Research was conducted by pyrolysis process at
500°C for 5 hours and the liquid smoke was collected in container for analyzes. Analysis of liquid smoke characteristics
included pH, specific gravity, acetic acid, phenol and other chemical component content using py-GCMS. The result
showed that the pH ranged from 2.68 to 4.34, specific gravity ranged from 0.83 to 1.04, acetate 0.65–13.09%, and
phenol content 0.19–2.50%. GCMS analysis showed chemical component diversity and its main component as identity
of specific liquid smoke from five wood species confirmed were acetic acid (acetic acid, ethylic acid), phenolic (phenol,
2,6-dimethoxy (CAS) 2,6-dimethoxyphenol), and carbamic acid. The chemical component of liquid smoke is expected
to be applied in wide variety of products based on product’s perspective, objectives and product targets that would be
achieved.
Article Details
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References
Akbar, A., Paindoman, R., & Coniwanti, P. (2013). Pengaruh variabel waktu dan temperatur terhadap pembuatan asap cair dari limbah kayu pelawan (Cyanometra cauliflora). Jurnal Teknik Kimia, 19(1), 1–8.
Alpian, Prayitno, T. A., Pramana, J., & Sutapa, G. (2014). Kualitas asap cair batang gelam (Melaleuca sp.). Jurnal Penelitian Hasil Hutan, 32(2), 83–92.
Ariestya, D. I., Swastawati, F., & Susanto, E. (2016). Antimicrobial activity of microencapsulation liquid smoke on tilapia (Oreochromis niloticus Linnaeus) meat for preservatives in cold storage (±5C°). Aquatic Procedia, 2nd International Symposium on Aquatic Products Processing and Health, ISAPPROSH 2015 7, 19–27. doi: 10.1016/j.aqpro.2016.07.003.
Asmawit, & Hidayati. (2016). Kelapa sawit proses redistilasi the characteristics of liquid smoke destilat from oil palm empty fruit bunches in the process redistilled. Majalah BIAM, 8–14.
Baimark, Y., & Niamsa, N. (2009). Study on wood vinegars for use as coagulating and antifungal agents on the production of natural rubber sheets. Biomass and Bioenergy, 33(6-7), 994–998. doi.org: 10.1016/j.biombioe.2009.04.001.
Ban, Y., Asakura, T., & Morita, Y. (2009). Reduction kinetics of Pu (IV) and Np (VI) by N, N-dimethylhydrazine, and its potential application in nuclear fuel reprocessing. Journal of Radioanalytical and Nuclear Chemistry, 279(2), 423–424. doi: 10.1007/s10967-007-7262-4.
Bossa, J. B., Theulé, P., Duvernay, F., Borget, F., & Chiavassa, T. (2008). Carbamic acid and carbamate formation in NH3 : CO2 ices – UV irradiation versus thermal processes. Astronomy & Astrophysics, 724, 719–724.
Cao, Y., Shi, Y., Bi, Y., Wu, K., Hu, S., & Wu, Y. (2018). Hydrodeoxygenation and hydroisomerization of palmitic acid over bi- functional Co / H-ZSM-22 catalysts. Fuel Processing Technology, 172(August 2017), 29–35. doi: 10.1016/j.fuproc.2017.09.020.
Cerezo, A., Tesfaye, W., Torija, M. J., Mateo, E., Garcı, M. C., & Troncoso, A. (2008). The phenolic composition of red wine vinegar produced in barrels made from different woods. Food Chemistry, 109, 606–615. doi: 10.1016/j.foodchem.2008.01.013
Choi, Y., Ahn, B.-J., & Kim, G. (2012). Bioresource technology extraction of chromium , copper , and arsenic from CCA-treated wood by using wood vinegar. Bioresource Technology, 120, 328–331. doi: 10.1016/j.biortech.2012.06.045.
dos Santos Alves, L. A. A., Lorenzo, J. M., Gonçalves, A. C. A., Alves dos Santos, B., Heck, R. T., Cichoski, J. A., & Campagnol, C. P. B. (2017). Impact of lysine and liquid smoke as fl avor enhancers on the quality of low-fat Bologna-type sausages with 50 % replacement of NaCl by KCl. Meat Science, 123, 50–56. doi: 10.1016/j.meatsci.2016.09.001.
Fachraniah, Foba, Z., & Rahmi, Z. (2009). Peningkatan kualitas asap cair dengan distilasi. Jurnal Reaksi, 7(14), 1–11.
Frey, J., Rusche, H., Schink, B., & Schleheck, D. (2016). Cloning , functional expression and characterization of a bifunctional 3-hydroxybutanal dehydrogenase / reductase involved in acetone metabolism by Desulfococcus biacutus. Biomed Central Microbiology, 1–9. doi: 10.1186/s12866-016-0899-9
Hagner, M., Penttinen, O., Tiilikkala, K., & Setälä, H. (2013). The effects of biochar, wood vinegar and plants on glyphosate leaching and degradation. European Journal of Soil Biology, 58, 1–7. doi: 10.1016/j.ejsobi.2013.05.002
Haji, A. G., Alim, Z., Lay, B. W., Sutjahjo, S. H., & Pari, G. (2007). Karakterisasi asap cair hasil pirolisis sampah organik padat. Jurnal Teknologi Industri Pertanian, 16(3), 111–118.
He, J., Yin, T., Chen, Y., Cai, L., & Tai, Z. (2015). Phenolic compounds and antioxidant activities of edible flowers of Pyrus pashia. Journal of Functional Foods, 17, 371–379. doi: 10.1016/j.jff.2015.05.045
Ho, C. W., Lazim, A. M., Fazry, S., & Zaki, U. K. H. H. (2016). Varieties, production, composition and health benefits of vinegars: A review. Food Chemistry, 221, 1621-1630. doi: 10.1016/j.foodchem.2016.10.128
Kim, H., & Lee, M. (2014). 1,2-Benzendiol isolated from persimmon roots and its structural analogues show antimicrobial activities against food-borne bacteria. Journal of the Korean Society for Applied Biological Chemistry, 57, 429–430. doi: 10.1007/s13765-014-4141-x.
Komarayati, S., Gusmailina, & Pari, G. (2011). Produksi cuka kayu hasil modifikasi tungku arang terpadu. Jurnal Penelitian Hasil Hutan, 29(3), 234–247.
Komarayati, S., & Wibowo, S. (2015). Karakteristik asap cair dari tiga jenis bambu. Jurnal Penelitian Hasil Hutan, 33(2), 167–174.
Lian, J., Garcia-perez, M., & Chen, S. (2013). Bioresource technology fermentation of levoglucosan with oleaginous yeasts for lipid production. Bioresource Technology, 133, 183–189. doi: 10.1016/j.biortech.2013.01.031.
Lingbeck, J. M., Cordero, P., Bryan, C. A. O., Johnson, M. G., Ricke, S. C., & Crandall, P. G. (2014). Functionality of liquid smoke as an all-natural antimicrobial in food preservation. Meat Science, 97(2), 197–206. doi: 10.1016/j.meatsci.2014.02.003.
Luo, Y., Guda, V. K., Steele, P. H., & Wan, H. (2016). Bio-oils to hydrocarbons in fixed-bed continuous. Bioresouces, 11, 4415–4431.
Mungkunkamchao, T., Kesmala, T., Pimratch, S., Toomsan, B., & Jothityangkoon, D. (2013). Scientia horticulturae wood vinegar and fermented bioextracts: natural products to enhance growth and yield of tomato (Solanum lycopersicum L.). Scientia Horticulturae, 154, 66–72. doi: 10.1016/j.scienta.2013.02.020
Nasruddin. (2015). Karakteristik asap cair yang ditambahkan ekstrak aroma daun pandan wangi (Pandanus amaryllifolius Roxb.). Jurnal Dinamika Penelitian Industri, 26(1), 19–31.
Newby, J. J., Peebles, R. A., & Peebles, S. A. (2005). Heavy atom structure and conformer stabilities of cyclopropyl carbinol from rotational spectroscopy and ab initio calculations. Journal of Molecular Structure, 740, 133–142. doi: 10.1016/j.molstruc.2005.01.042.
Nitbani, F. O., Jumina, Siswanta, D., & Solikhah, N. E. (2016). Isolation and antibacterial activity test of lauric acid from crude coconut oil (Cocos nucifera L .). Procedia Chemistry, 18, 132–140. doi: 10.1016/j.proche.2016.01.021.
Nunkaew, T., Kantachote, D., & Chaiprapat, S. (2016). Use of wood vinegar to enhance 5-aminolevulinic acid production by selected Rhodopseudomonas palustris in rubber sheet wastewater for agricultural use. Saudi Journal of Biological Science. doi: 10.1016/j.sjbs.2016.01.028.
Opdyke, D. L. (1972). Monographs on fragrance raw materials Dihydrojasmone. Food and Cosmetics Toxiyology, 12(4), 1972.
Oramahi, H. ., Diba, F., & Nurhaida. (2014). New bio preservatives from lignocelluloses biomass bio-oil for anti termites Coptotermes curvignathus Holmgren. Procedia Environmental Sciences, 4th International Conference on Sustainable Future for Human Security, Sustain 2013, 20, 778–784. doi: 10.1016/j.proenv.2014.03.094.
Oramahi, H. A, & Diba, F. (2013). The 3rd international conference on sustainable future for human security maximizing the production of liquid smoke from bark of durio by studying its potential compounds. Procedia Environmental Sciences, The 3rd International Conference on Sustainable Future for Human Security, Sustain 2012, 17, 60–69. doi: 10.1016/j.proenv.2013.02.012.
Pamori, R., Efendi, R., & Restuhadi, F. (2015). Karakteristik asap cair dari pirolisis limbah sabut kelapa muda. Sagu, 14(2), 43–50.
Prinsen, P., Luque, R., & González-arellano, C. (2018). Microporous and mesoporous materials zeolite catalyzed palmitic acid esteri fi cation. Microporous and Mesoporous Materials, 262, 133–139. doi: 10.1016/j.micromeso.2017.11.029.
Rakhsit, K. P., Voolapalli, K. R., & Upadhyayula, S. (2018). Acetic acid hydrogenation to ethanol over supported Pt-Sn catalyst: Effect of bronsted acidity on product selectivity. Molecular Catalysis, 448, 78–90. doi: 10.1016/j.mcat.2018.01.030.
Satriadi, T., Jauhari, A., & Ariandi, M. (2010). Perbandingan rendemen cuka kayu (Wood Vinegar) jelutung (Dyera spp.) berdasarkan ukuran bahan baku. Jurnal Hutan Tropis, 11(30), 47–55.
Simangunsong, B. C. H., Sitanggang, V. J., Manurung, E. G. T., Rahmadi, A., Moore, G. A., & Aye, L. (2017). Potential forest biomass resource as feedstock for bioenergy and its economic value in Indonesia. Forest Policy and Economics, 81, 10–17. doi: 10.1016/j.forpol.2017.03.022.
Soares, J. M., Franklin, P., Saorin, B. M., Brustolin, A. P., Cansian, L., & Valduga, E. (2016). Antimicrobial and antioxidant activity of liquid smoke and its potential application to bacon. Innovative Food Science and Emerging Technologies, 38(A), 189-197.
Stein, U. H., Wimmer, B., Ortner, M., Fuchs, W., & Bochmann, G. (2017). Maximizing the production of butyric acid from food waste as a precursor for ABE-fermentation. Science of the Total Environment, 598, 993–1000. doi: 10.1016/j.scitotenv.2017.04.139
Swastawati, F., Boesono, H., Susanto, E., & Indah, A. (2016). Changes of amino acids and quality in smoked milkfish [Chanos chanos (Forskal)] processed by different redestilation methods of corncob liquid smoke. Aquatic Procedia, 2nd International Symposium on Aquatic Product Processing and Health ISAPPROSH 2015, 7, 100–105. doi: 10.1016/j.aqpro.2016.07.013.
Sweidan, A., Chollet-krugler, M., Weghe, P. Van De, Chokr, A., Tomasi, S., Bonnaure-mallet, M., & Bousarghin, L. (2016). Design, synthesis and biological evaluation of potential antibacterial butyrolactones. Bioorganic & Medicinal Chemistry, 24(22), 5823–5833. doi: 10.1016/j.bmc.2016.09.040.
Thy, P., Barfod, G. H., Cole, A. M., Brown, E. L., Jenkins, B. M., & Lesher, C. E. (2017). Trace metal release during wood pyrolysis. Fuel, 203, 548–556. doi: 10.1016/j.fuel.2017.04.050.
Vachlepi, A., & Suwardin, D. (2015). Characterization of iron metal corrosion in liquid smoke coagulant. Procedia Chemistry, International Symposium on Applied Chemistry 2015 (ISAC 2015), 16, 420–426. doi: 10.1016/j.proche.2015.12.073.
Wang, J., Zhan, P., Li, Z., Liu, H., Clercq, E. De, Pannecouque, C., & Liu, X. (2014). Chemistry discovery of nitropyridine derivatives as potent HIV-1 non-nucleoside reverse transcriptase inhibitors via a structure-based core refining approach. European Journal of Medicinal Chemistry, 76, 531–538. doi: 10.1016/j.ejmech.2014.02.047.
Wang, J., Zheng, J., Wang, J., & Lu, Z. (2018). Industrial crops & products: A separation and quantification method of levoglucosan in biomass pyrolysis. Industrial Crops & Products, 113, 266–273. doi: 10.1016/j.indcrop.2018.01.045.
Wang, Z., Lin, W., Song, W., & Yao, J. (2010). Preliminary investigation on concentrating of acetol from wood vinegar. Energy Conversion and Management, 51(2), 346–349. doi: 10.1016/j.enconman.2009.09.031.
Wee, J. S., Chai, A. B., & Ho, J. (2017). Fabrication of shape memory natural rubber using palmitic acid. Journal of King Saud University - Science. 29(4), 494-501. doi: 10.1016/j.jksus.2017.09.003.
Wibowo, S. (2012). Karakteristik asap cair tempurung nyamplung. Jurnal Penelitian Hasil Hutan, 30(3), 218–227.
Wu, Q., Zhang, S., Hou, B., Zheng, H., Deng, W., Liu, D., & Tang, W. (2015). Study on the preparation of wood vinegar from biomass residues by carbonization process. Bioresource Technology, 179, 98–103. doi: 10.1016/j.biortech.2014.12.026
Xu, X., Jiang, E., Li, B., Wang, M., Wang, G., Ma, Q., … Guo, X. (2013). Hydrogen production from wood vinegar of Camellia oleifera Shell by. Catalysis Communication, 39, 106–114. doi: 10.1016/j.catcom.2013.04.024.
Zatta, L., Ramos, L. P., & Wypych, F. (2013). Acid-activated montmorillonites as heterogeneous catalysts for the esterification of lauric acid acid with methanol. Applied Clay Science, 80-81, 236–244. doi: 10.1016/j.clay.2013.04.009.
Zhang, M., Yao, R., Jiang, H., Li, G., & Chen, Y. (2017). Applied surface science insights into the mechanism of acetic acid hydrogenation to ethanol on Cu ( 111 ) surface. Applied Surface Science, 412, 342–349. doi: 10.1016/j.apsusc.2017.03.222.
Zhang, Y., Ye, C., Guo, C., Gan, C., & Tong, X. (2018). In2O3-modified Cu / SiO 2 as an active and stable catalyst for the hydrogenation of methyl acetate to ethanol. Chinese Journal of Catalysis, 39(1), 99–108. doi: 10.1016/S1872-2067(17)62932-2.
